[astro-ph.GA] Carbocations are key species in interstellar chemistry, providing entry points for building larger hydrocarbons. CH+, and more recently, CH3+, have been detected. Other carbocations await detection to provide a […]
organic chemistry
Posted inAstrochemistry
MINDS: Complementary Inclinations In The Binary Ssystem HK Tau Reveal Gas- And Ice-phase Chemistry
[astro-ph.EP] HK Tau is a roughly equal mass pre-main sequence binary system consisting of a low-inclination primary (57 deg) and an edge-on (83 deg) secondary. We present JWST/MIRI observations targeting […]
Posted inAstrochemistry
Dual Use Technology – An Astrochemistry Spin Off
Editor’s note: many of the tools that are used in astronomy to conduct analyses of chemistry in space – astrochemistry – utilize technology that has had long-standing applications in a […]
Posted inAstrochemistry
Charge Transfer From Ammonia Neutralizes Propylene Oxide Cations: Implications For The Astrochemistry Of Chiral Molecules
[astro-ph.GA] To date only one chiral species, propylene oxide, has been observed in the interstellar medium but little is known about the chemistry that leads to a detectable abundance of […]
Posted inBiochemistry & Organic Chemistry
Unraveling The Building Blocks Of Earth’s Pigments
[Ohio State] Although they are some of the most widespread substances on Earth, not much is known about eumelanin, or natural organic matter (NOM) — a dark-colored substance formed by […]
Posted inAstrochemistry
Theoretical and Experimental IR Spectra of Astronomical PAHs and PANHs in the 2000–1650 cm–1 Range (∼5–6 μm)
[ACS Earth and Space Chemistry] Recent James Webb Space Telescope observations reveal unprecedented details in the 2000–1650 cm–1 (∼5–6 μm) region, including the well-known 5.25 and 5.75 μm bands.
Posted inAstrochemistry
Theoretical Determination Of The Binding Energies Of Methanol And Related Species Onto Amorphous Solid Water Ice
[astro-ph.GA] The formation and survival of complex organic molecules (COMs) in cold interstellar environments depends on their interactions with icy dust grain surfaces.
Posted inAstrochemistry
Probing Outflow Physics Through CH3CN And CH3OH Chemistry
[astro-ph.GA] Chemical correlations between molecules provide powerful diagnostics to probe the physical conditions of protostellar outflows. In particular, the relationship between methanol (CH3OH) and methyl cyanide (CH3CN) offers a promising […]
Posted inUncategorized
A Look At Eight Outbursts Of Comet 7P/Pons-Winnecke
Cometary outbursts may be used as a means to infer the physical processes occurring on cometary nuclei. To that end, we studied eight outbursts of comet 7P/Pons-Winnecke identified between 2021 […]
Posted inAstrochemistry
Reaction Mechanisms and Kinetics of CN and CCH with H2CS: Implications for Interstellar Sulfur Chemistry
We report an ab initio and master-equation investigation of the gas-phase reactions of thioformaldehyde (H2CS) with CN and CCH radicals, motivated by the recent detection of the S-containing species HCSCN […]