[astro-ph.EP] Hydrogen-isotopologues are commonly used to trace the chemical processing and origin of hydrogen-bearing species throughout the Universe, however, their abundance remains unconstrained for extrasolar planets.

Here, we report atmospheric retrieval evidence for the deuterated water molecule HDO in an exoplanet atmosphere, retrieved from James Webb Space Telescope transmission spectra of the hot Jupiter WASP-39 b, resulting in a deuterium-to-hydrogen ratio in water of 4.0+1.3−1.1×10−3.

The inferred value is substantially higher than those measured for the Solar System gas giants and overlaps numerically with values reported for some protostellar and inner Solar System environments.

This enrichment may reflect either inherited water-rich material accreted beyond the snow line or isotopic processing in the observable atmosphere through transport, photochemistry, and subsequent escape.

Fabian Gruebel (1,2), Karan Molaverdikhani (2,3), Barbara Ercolano (1,2,3), Katy L. Chubb (4), Paola Caselli (3,2), Tommaso Grassi (3,2), Rosa Arenales-Lope (1,2), Dwaipayan Dubey (1,2) ((1) Ludwig-Maximilians-Universitaet Muenchen, Muenchen, Germany, (2) Exzellenzcluster Origins, Garching, Germany, (3) Max-Planck-Institut fuer Extraterrestrische Physik, Garching, Germany, (4) HH Wills Physics Laboratory, University of Bristol, Bristol, UK)

Comments: Under review, comments welcome
Subjects: Earth and Planetary Astrophysics (astro-ph.EP)
Cite as: arXiv:2607.19579 [astro-ph.EP] (or arXiv:2607.19579v1 [astro-ph.EP] for this version)
https://doi.org/10.48550/arXiv.2607.19579
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Submission history
From: Barbara Ercolano Prof
[v1] Tue, 21 Jul 2026 21:14:36 UTC (4,640 KB)
https://arxiv.org/abs/2607.19579

Astrobiology,

Explorers Club Fellow, ex-NASA Space Station Payload manager/space biologist, Away Teams, Journalist, Lapsed climber, Synaesthete, Na’Vi-Jedi-Freman-Buddhist-mix, ASL, Devon Island and Everest Base Camp...

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