[JACS] Carbonaceous solids with pores in the nanometer domain are of great technological importance owing to their amenability to sorption/separation, catalysis, and electrochemical applications.
organic chemistry
Autonomous Multi-Agent Reconstruction of Prebiotic Reaction Networks Reveals Organizational Features of Amino Acid Synthesis
[chemrxiv.org] Decades of origin-of-life research have uncovered hundreds of prebiotically plausible reactions across hydrothermal, surface, and biochemical environments, yet this knowledge remains fragmented across chemistry, geochemistry, and astrobiology. Here we […]
Molecular Assembly As A Universal Biosignature Measurable By Mass Spectrometry
[PNAS] Detecting life beyond Earth requires biosignatures that do not depend on the chemistry of known organisms.
Infrared Spectroscopy and Photochemistry of Aromatic Nitriles in Para-Hydrogen Matrices
[astro-ph.SR] Motivated by recent detections of several aromatic nitriles in Taurus Molecular Cloud-1, we report laboratory and theoretical investigations of the vibrational spectroscopy and photochemistry of singly and doubly cyano-substituted […]
First Detection Of C2H+ In The Interstellar Medium
[astro-ph.GA] Despite the detection of nearly 350 molecules in the interstellar medium, almost half of which are carbon chains, the pathways that build molecular complexity remain poorly understood.
Photochemistry Of Interstellar Ice Forming Complex Organic Molecules
[astro-ph.GA] Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by […]
Biosignature Reservoirs In The Rozel Point Tar Seeps At Great Salt Lake, Utah
[Frontiers in Microbiology] On the north shore of Great Salt Lake, Utah, USA, naturally occurring tar seeps at Rozel Point provide an opportunity to study a petroleum-rich environment adjacent to […]
Reconstructing Ancient Protein Alphabets: What Can We Truly Infer?
[Trends in Genetics] The canonical amino acid alphabet has remained remarkably stable since life’s early stages, yet the factors that shaped its emergence remain debated. Early views emphasized prebiotic availability […]
Formation Of Nitriles And Isonitriles By The Heavy-ion Irradiation Of Propionitrile In N2-rich Astrophysical Ices
[astro-ph.EP] Context. Nitriles are key nitrogen-bearing organic molecules in dense clouds, star-forming regions, and nitrogen-rich icy environments. Understanding their stability and chemical evolution under energetic processing is essential for understanding […]
A JWST Study of Stardust. I. Infrared Spectroscopy of Comet 81P/Wild 2 and Overall Composition
[astro-ph.EP] We report observations of comet 81P/Wild 2, target of the Stardust sample return mission, on UT 2023 March 20 and 24 at a heliocentric distance (rH) of 1.85 au […]
