Chemical Models of Interstellar Glycine and Adenine Precursor Aminoacetonitrile (NH2CH2CN)

Aminoacetonitrile (AAN), also known as glycinenitrile, has been suggested as a possible precursor of glycine and adenine in the interstellar medium. Here we present the chemical modeling of AAN and its isomers in hot cores using the three-phase chemical model NAUTILUS with the addition of over 300 chemical reactions of the three AAN isomers and related species. Our models predicted a peak gas phase abundance of AAN reaching the order of 10-8, which is consistent with observation towards Sgr B2(N).

Regarding the reaction pathways of AAN and its isomers, we found that AAN is primarily formed via free radical reactions on grain surfaces during the early evolutionary stages. Subsequently, it is thermally desorbed into the gas phase as the temperature rises and is then destroyed by positive ions and radicals in gas phase. The isomers of AAN are formed through the hydrogenation reaction of CH3NCN on the grain surface and via electron recombination reactions of ion C2H5N2+ in gas phase.

We speculate that there is a possibility for NCCN and AAN to react with each other, eventually leading to the formation of adenine in hot cores. However, further investigation is required to understand the efficiency of grain surfaces in adenine formation, through theoretical calculations or laboratory experiments in future research.

Aminoacetonitrile — Wikipedia

Xia Zhang, Donghui Quan, Xiaohu Li, Jarken Esimbek, Fangfang Li, Yan Zhou, Dalei Li

Comments: 15 pages,8 figures,5 tables,accepted for publication in MNRAS
Subjects: Astrophysics of Galaxies (astro-ph.GA)
Cite as: arXiv:2408.11776 [astro-ph.GA] (or arXiv:2408.11776v1 [astro-ph.GA] for this version)
https://doi.org/10.48550/arXiv.2408.11776
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Submission history
From: Xia Zhang
[v1] Wed, 21 Aug 2024 17:04:49 UTC (822 KB)
https://arxiv.org/abs/2408.11776

Astrobiology