Nitrogen-bearing molecules are more difficult to observe than oxygen-bearing ones, mainly due to the lower abundance of nitrogen in the interstellar medium.
astro-ph.GA
Aromatic Rings In The Central Molecular Zone: Benzonitrile
In recent years, several aromatic molecules (benzene-based rings) have been detected in the cold molecular cloud TMC-1, with its CN-derivative, benzonitrile (c-C6H5CN), also identified in other nearby cold sources.
LMA Observations Of Acetone In Hot Cores
Acetone (CH3COCH3) is a ubiquitous interstellar molecule, and serves as an important tracer of hot core chemistry. We conducted a line survey of acetone and its precursor acetaldehyde (CH3CHO) towards […]
The Reaction Between Atomic Carbon And Molecular Nitrogen As A Source Of Cyanamide And Carbodiimide On Interstellar Ices
Reactions occurring on the ice-covered surfaces of interstellar dust grains are considered to be among the most important sources of complex species in the interstellar medium. Despite this, molecules such […]
Ice as a Photochemical Shield: Adsorption Energetics and Spectroscopic Modulation of Interstellar Thiocyanates HCSCN and HCSCCH in TMC-1
The recent detections of thioformyl cyanide (HCSCN) and propynethial (HCSCCH) in TMC-1 provide critical insights into the interstellar sulfur inventory, yet their sequestration and survivability on dust grain mantles remain […]
Methanimine As A Sink In The HCN And HNC Solid State Hydrogenation Network
We aim to provide a systematic and quantitative description of the hydrogenation network connecting HCN and HNC to methylamine on interstellar water ices, while identifying dominant pathways and bottlenecks.
A Post-perihelion Constraint On The CO2/H2O Ratio Of Interstellar Comet 3I/ATLAS From [O I] Forbidden Lines
We present high-resolution optical spectroscopy of interstellar comet 3I/ATLAS (C/2025 N1) obtained with the High Dispersion Spectrograph mounted on the Subaru Telescope on UT 2026 January 7, when the comet […]
Interstellar Stereoisomerism
The increasing detection of new molecules in the interstellar medium (ISM) shows that stereoisomerism is a fundamental contributor to interstellar molecular complexity.
Benchmarking Astrochemistry Paradigms: Relative Absence of C6H5CN+ in the Diffuse ISM
The detectability of C6H5CN+ (benzonitrile cation) in the diffuse ISM is re-evaluated. A holistic evidentiary framework suggests C6H5CN+ is relatively absent in the diffuse ISM owing to the following concurrently: […]
The SPHEREx Ices Investigation: An Overview
SPHEREx is a NASA mission designed to perform an all-sky spectroscopic survey in the 0.75 – 5 μm wavelength range. Its primary science objectives are to investigate: (1) inflationary cosmology, […]
