[astro-ph.GA] Sulfur is the tenth most abundant element in space, yet it is strongly depleted in the gas phase of dense interstellar regions, suggesting sequestration in dust grain components that […]
Interstellar
Chemical Diversity Of Dense Cores In Orion B: The Role Of The Environment
[Astronomy & Astrophysics] Context. Pre-stellar cores are the sites of the earliest stages of star formation. Dust continuum observations are often used to identify and characterise their properties yet only […]
Precise C-N-O Abundances of Individual Galaxies In The First Billion Years From Ultra-Deep, Rest-UV-to-Optical JWST Spectroscopy
[astro-ph.GA] We present ultra-deep JWST/NIRSpec 𝑅 ∼ 1000 spectroscopy of nine star-forming galaxies at 𝑧 = 6.0 − 8.3 in the GOODSN field, drawn from the Origins of Metal Enrichment […]
Secondary Ion-Ice Chemistry in UV-Irradiated Oxygen Ice: New Astrochemical Models Including Bulk Ionic Species
[ACS Earth Space Chemistry] Although energetic and nonenergetic processing of interstellar dust grain surfaces and ice is thought to be one of the dominant mechanisms for the extraterrestrial synthesis of […]
Nonequilibrium Formation of Pyridine (C5H5N) in Interstellar Ice Analogs: Implications for Biorelevant Nitrogen Heterocycles in Ryugu and Bennu
[Journal of the American Chemical Society] Biorelevant nitrogen heterocycles, including the five canonical nucleobases found in RNA and DNA, have recently been identified in samples returned from the carbonaceous asteroids […]
Modeling The Radiolysis In H2O:HCOOH ice: Connecting Laboratory Experiments With Astronomical Measurements
[RSC Advances] We present a computational study of radiolytic chemistry and desorption dynamics in astrophysical ice composed of H2O:HCOOH (1 : 1), irradiated with Ni11+ ions at 46 MeV and […]
Nonequilibrium Formation of C4 Carbonyls in Interstellar Ices Linked to Amino Acids
[ACS Central Science] Complex organic molecules in interstellar ices and carbonaceous asteroids record key steps in the chemical evolution toward life, yet the origin of branched carbonyl compounds a fundamental […]
Laboratory Evidence that Methanol-Rich Ice Mantles Lower Methyl Formate Binding Energies
[astro-ph.IM] Complex organic molecules are widely detected in star-forming regions and are important precursors to prebiotic species. Because these molecules are thought to form primarily within icy grain mantles, their […]
Thioacetaldehyde (CH3CHS) On Interstellar Ices: A Key Molecule To Unravel Two Chemical Dichotomies In The ISM
[astro-ph.GA] Thioacetaldehyde (CH3CHS), recently detected in TMC-1, has an abundance approximately 36 times lower than its oxygen analog, acetaldehyde (CH3CHO). This makes the CH3CHS/CH3CHO pair the one with the largest […]
Interstellar Disparity: N- vs O-bearing Molecules: A Multidisciplinary Perspective across Interstellar Environments
[astro-ph.GA] Observations of O- and N-bearing molecules reveal systematic chemical differentiation across a wide range of interstellar environments.
