A Highly Carbon-Rich Dayside and Disequilibrium Chemistry in the Ultra-Hot Jupiter WASP-19b

Ultra-hot Jupiters (UHJs) offer exceptional opportunities for detailed atmospheric characterization via emission spectroscopy.
Here we present a comprehensive analysis of the dayside atmosphere of WASP-19b—one of the shortest-period UHJs—using archival JWST NIRSpec/PRISM observations spanning 0.6-5.3 μm. We report robust detections of H2O (16.44 σ), CO (5.47 σ), and CO2 (10.72 σ), along with marginal detections of CH4 (3.76 σ) and C2H2 (2.45 σ).
The retrieved composition reveals a highly carbon-rich atmosphere with a tightly constrained super-solar C/O ratio of 0.94±0.03. Elevated abundances of carbon-bearing species provide strong evidence (11.69 σ) for disequilibrium chemistry.
We also detect condensate clouds, likely Al2O3(c), at high significance (17.28 σ), and constrain the atmospheric metallicity to 1.7+1.2−0.7 × solar. These results establish a precise benchmark for modeling dayside conditions in extreme irradiated atmospheres and demonstrate JWST’s transformative capabilities for exoplanet science.
Suman Saha, James S. Jenkins
Comments: 32 pages, including 11 figures and 3 tables. Under review—comments are warmly welcomed!
Subjects: Earth and Planetary Astrophysics (astro-ph.EP)
Cite as: arXiv:2507.02797 [astro-ph.EP] (or arXiv:2507.02797v1 [astro-ph.EP] for this version)
https://doi.org/10.48550/arXiv.2507.02797
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Submission history
From: Suman Saha
[v1] Thu, 3 Jul 2025 16:58:55 UTC (17,043 KB)
https://arxiv.org/abs/2507.02797
Astrobiology