Resolving Desorption Of Complex Organic Molecules In A Hot Core: Transition From Non-thermal To Thermal Desorption Or Two-step Thermal Desorption?

By Keith Cowing
June 22, 2022
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Resolving Desorption Of Complex Organic Molecules In A Hot Core: Transition From Non-thermal To Thermal Desorption Or Two-step Thermal Desorption?
Continuum maps at 242 GHz (Sánchez-Monge et al. 2017) shown in colour scale and at 99.2 GHz (ReMoCA) shown with teal contours. The contour steps start at 4σ and then increase by a factor of 2 with σ = 0.4 K the rms noise level of the continuum map at 99.2 GHz. The black cross shows the phase centre of the ReMoCA observations. The white cross shows the intensity-weighted 3 mm continuum peak determined in this work. Orange crosses indicate 1.3 mm continuum sources from Sánchez-Monge et al. (2017), cyan crosses the continuum peaks of the hot cores N1 and N2 as well as the line density peak of N3 reported by Bonfand et al. (2017) on the basis of the EMoCA survey at 1.600 resolution, and pink crosses HII regions reported by Gaume et al. (1995) (K1–K6, K9.69) and De Pree et al. (2015) (K7) with the VLA. The black box indicates the region for which spectral indices are determined as shown in Fig. 2. The respective synthesised beams for both maps are shown in the lower right corner.

Using the high angular resolution provided by the ALMA interferometre we want to resolve the COM emission in the hot molecular core Sagittarius B2(N1) and thereby shed light on the desorption process of Complex Organic Molecules (COMs) in hot cores.

We use data taken as part of the 3 mm spectral line survey Re-exploring Molecular Complexity with ALMA (ReMoCA) to investigate the morphology of COM emission in Sagittarius B2(N1). Spectra of ten COMs are modelled under the assumption of LTE and population diagrams are derived for positions at various distances to the south and west from the continuum peak. Based on this analysis, resolved COM rotation temperature and COM abundance profiles are derived. Based on the morphology, a rough separation into O- and N-bearing COMs can be done. Temperature profiles are in agreement with expectations of protostellar heating of an envelope with optically thick dust.

Abundance profiles reflect a similar trend as seen in the morphology and, to a great extent, agree with results of astrochemical models that, besides the co-desorption with water, predict that O-bearing COMs are mainly formed on dust grain surfaces at low temperatures while at least some N-bearing COMs and CH3CHO are substantially formed in the gas phase at higher temperatures. Our observational results, in comparison with model predictions, suggest that COMs that are exclusively or to a great extent formed on dust grains desorb thermally at ~100 K from the grain surface likely alongside water.

Non-zero abundance values below ~100 K suggest that another desorption process is at work at these low temperatures: either non-thermal desorption or partial thermal desorption related to lower binding energies experienced by COMs in the outer, water-poor ice layers. In either case, this is the first time that the transition between two regimes of COM desorption has been resolved in a hot core.

Laura A. Busch, Arnaud Belloche, Robin T. Garrod, Holger S. P. Müller, Karl M. Menten

Comments: Accepted for publication in A&A
Subjects: Astrophysics of Galaxies (astro-ph.GA)
Cite as: arXiv:2206.11174 [astro-ph.GA] (or arXiv:2206.11174v1 [astro-ph.GA] for this version)
Submission history
From: Laura Ann Busch
[v1] Wed, 22 Jun 2022 15:32:03 UTC (5,626 KB)

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