Astrochemistry

10/5 NAI Director's Seminar

By Keith Cowing
September 22, 2009

Danny Glavin (speaker) and Jason Dworkin, “Southpaw Solar System: L-Amino Acid Excesses in Meteorites and the Implications for the Origin of Homochirality on Earth”

Abstract: Meteorites provide a record of the chemical processes that occurred in the early solar system before life began on Earth. The delivery of organic matter, including amino acids, by carbonaceous meteorites could have been an important source of the early Earth’s prebiotic organic inventory. The earlier discovery of slight to significant excesses for several indigenous left handed

Large excesses of L-isovaline were found in several aqueously altered meteorites, but not in the most primitive unaltered CR2 meteorites. These findings are inconsistent with UV-circularly polarized light as the primary mechanism for L-isovaline enrichment and indicate that amplification of a small initial imbalance occurred during an extended aqueous alteration phase on the meteorite parent bodies. The fact that only L-amino acid excesses have been found in meteorites analyzed so far (no D-excesses) may indicate that the origin of life on Earth and possibly elsewhere in our solar system was biased toward L-amino acids from the very beginning.

For more information and participation instructions: http://astrobiology.nasa.gov/nai/seminars/detail/158 Source: NAI Newsletter

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