Europa

The Role Of Ammonia In The Distribution Of Volatiles In The Primordial Hydrosphere Of Europa

By Keith Cowing
Status Report
astro-ph.EP
December 2, 2024
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The Role Of Ammonia In The Distribution Of Volatiles In The Primordial Hydrosphere Of Europa
Model scheme representation. The model represents the dissolution of volatiles from the primordial atmosphere into the ocean. The liquid-vapor equilibrium of the volatile species is coupled to a chemical equilibrium model that considers the speciation of H2O, CO2, and NH3. This coupled approach allows the partitioning of the volatiles between the atmosphere and the ocean to be determined, taking into account both physical and chemical equilibrium. This model does not account for water-rock interactions between the ocean and silicate mantle. — astro-ph.EP

The presence of a hydrosphere on Europa raises questions about its habitability, and studies of its volatile inventory can provide insight into its formation process. Different scenarios suggest that Europa’s volatiles could be derived from cometary ices or devolatilized building blocks.

The study of post-accretion processes, in particular the “open ocean” phase that likely occurred before the formation of the icy crust, is crucial to distinguish these origins, as this phase is likely to have influenced the volatile inventory. The abundance of ammonia in Europa’s building blocks is also crucial for understanding the composition of its ocean and primordial atmosphere.

We aim to investigate ocean-atmosphere equilibrium during the post-accretion period by varying the ammonia fraction in the atmosphere. Our model evaluates the vapor-liquid equilibrium of water and volatiles, as well as the chemical equilibrium within the ocean, to study Europa’s early hydrosphere.

We explore two initial conditions: one in which Europa’s hydrosphere originates from comet-like building blocks, and another in which it forms in equilibrium with a thick, CO2-rich atmosphere.

In both scenarios, the initial ratio of accreted CO2 to NH3 determines the magnitude of their partial pressures in Europa’s early atmosphere. If this ratio exceeds a certain threshold (set to 10−4 in this study), the atmosphere will be CO2-rich; otherwise, it will be CO2-depleted by multiple orders of magnitude.

Overall, our work provides a initial assessment of the distribution of primordial volatiles in Europa’s primitive hydrosphere, and provides a baseline for interpreting data from the upcoming Europa Clipper mission.

Alizée Amsler Moulanier, Olivier Mousis, Alexis Bouquet, Christopher R. Glein

Comments: 15 pages, 5 figures. Accepted for publication in Planetary Science Journal
Subjects: Earth and Planetary Astrophysics (astro-ph.EP)
Cite as: arXiv:2411.19743 [astro-ph.EP] (or arXiv:2411.19743v1 [astro-ph.EP] for this version)
https://doi.org/10.48550/arXiv.2411.19743
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Submission history
From: Alizée Amsler Moulanier
[v1] Fri, 29 Nov 2024 14:40:26 UTC (547 KB)
https://arxiv.org/abs/2411.19743

Astrobiology,

Explorers Club Fellow, ex-NASA Space Station Payload manager/space biologist, Away Teams, Journalist, Lapsed climber, Synaesthete, Na’Vi-Jedi-Freman-Buddhist-mix, ASL, Devon Island and Everest Base Camp veteran, (he/him) 🖖🏻