Meteorites Reveal The Likely Origin Of Earth’s Volatile Chemicals

By Keith Cowing
Press Release
Imperial College London
January 27, 2023
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Meteorites Reveal The Likely Origin Of Earth’s Volatile Chemicals
Zn isotope anomalies for each meteorite group and the BSE, in ε i Zn notation. Data are plotted for different groups of meteorites and the BSE, see the legend. Carbonaceous chondrites (CI, CM, CV, CO chondrites) and non-carbonaceous group meteorites [ECs, including two EHs (high iron), OCs, including H (high iron), L (low iron), and LL (low iron, low metal) chondrites, and IAB complex irons] have complimentary patterns with CCs enriched in 68 Zn and 70 Zn and depleted in 64 Zn. relative to the BSE which has εi Zn = 0. NCs have the opposite pattern, with depletions in 68 Zn and 70 Zn and enrichments in 64 Zn. There is no data for ε 66 Zn and ε 67 Zn because these isotopes are used for internal normalization. The meteorite and BSE data are listed in Table S2; error bars indicate ±2se. — Imperial College London

By analysing meteorites, Imperial researchers have uncovered the likely far-flung origin of Earth’s volatile chemicals, some of which form the building blocks of life.

They found that around half the Earth’s inventory of the volatile element zinc came from asteroids originating in the outer Solar System – the part beyond the asteroid belt that includes the planets Jupiter, Saturn, and Uranus. This material is also expected to have supplied other important volatiles such as water.

Volatiles are elements or compounds that change from solid or liquid state into vapour at relatively low temperatures. They include the six most common elements found in living organisms, as well as water. As such, the addition of this material will have been important for the emergence of life on Earth.

Prior to this, researchers thought that most of Earth’s volatiles came from asteroids that formed closer to the Earth. The findings reveal important clues about how Earth came to harbour the special conditions needed to sustain life.

Senior author Professor Mark Rehkämper, of Imperial College London’s Department of Earth Science and Engineering, said: “Our data show that about half of Earth’s zinc inventory was delivered by material from the outer Solar System, beyond the orbit of Jupiter. Based on current models of early Solar System development, this was completely unexpected.”

Previous research suggested that the Earth formed almost exclusively from inner Solar System material, which researchers inferred was the predominant source of Earth’s volatile chemicals. In contrast, the new findings suggest the outer Solar System played a bigger role than previously thought.

Professor Rehkämper added: “This contribution of outer Solar System material played a vital role in establishing the Earth’s inventory of volatile chemicals. It looks as though without the contribution of outer Solar System material, the Earth would have a much lower amount of volatiles than we know it today – making it drier and potentially unable to nourish and sustain life.”

The findings are published today in Science.

To carry out the study, the researchers examined 18 meteorites of varying origins – eleven from the inner Solar System, known as non-carbonaceous meteorites, and seven from the outer Solar System, known as carbonaceous meteorites.

For each meteorite they measured the relative abundances of the five different forms – or isotopes – of zinc. They then compared each isotopic fingerprint with Earth samples to estimate how much each of these materials contributed to the Earth’s zinc inventory. The results suggest that while the Earth only incorporated about ten per cent of its mass from carbonaceous bodies, this material supplied about half of Earth’s zinc.

The researchers say that material with a high concentration of zinc and other volatile constituents is also likely to be relatively abundant in water, giving clues about the origin of Earth’s water.

First author on the paper Rayssa Martins, PhD candidate at the Department of Earth Science and Engineering, said: “We’ve long known that some carbonaceous material was added to the Earth, but our findings suggest that this material played a key role in establishing our budget of volatile elements, some of which are essential for life to flourish.”

Next the researchers will analyse rocks from Mars, which harboured water 4.1 to 3 billion years ago before drying up, and the Moon. Professor Rehkämper said: “The widely held theory is that the Moon formed when a huge asteroid smashed into an embryonic Earth about 4.5 billion years ago. Analysing zinc isotopes in moon rocks will help us to test this hypothesis and determine whether the colliding asteroid played an important part in delivering volatiles, including water, to the Earth.”

This work was funded by the Science and Technology Facilities Council (STFC – part of UKRI) and Rayssa Martins is funded by an Imperial College London Presidents’ PhD Scholarship.

Nucleosynthetic isotope anomalies of zinc in meteorites constrain the origin of Earth’s volatiles, Science

Astrobiology, Astrochemistry

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